期刊
JOURNAL OF POWER SOURCES
卷 243, 期 -, 页码 790-795出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2013.06.106
关键词
Lanthanum nickelate; Ruddlesden Popper; Composite; Solid oxide fuel cell; Cathode
资金
- EPSRC
Ruddlesden-Popper phases of the formula (LaNiO3)(n)LaO are potential materials for intermediatetemperature solid oxide fuel cell cathodes. The n = 1 phase La2NiO4+delta is known to have good ionic conductivity but its performance as a single-phase cathode is limited by its electronic conductivity. The n = 3 phase La4Ni3O10-delta is known to have good total conductivity but has been little-explored as a cathode. In this study we explore composite electrodes of these two materials with a view to taking advantage of their complimentary properties. The performance of these electrodes is compared to that of the single-phase end-members and is found to be improved above 600 degrees C. A 50:50 wt.% La2NiO4+delta:La4Ni3O10-delta mix gave the best performance and represents best-in-class for these materials. (C) 2013 Elsevier B.V. All rights reserved.
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