期刊
JOURNAL OF POWER SOURCES
卷 244, 期 -, 页码 601-605出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2013.01.055
关键词
Porous nickel-tin foam; Anode electrode; Hydrogen evolution reaction; Dendrite structures; Lithium-ion battery
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2012-0001525]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10047681] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2011-0010546] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A highly porous three-dimensional Ni-Sn alloy foam is fabricated by electro-deposition accompanied by hydrogen evolution reaction. This foam can evolve into porous and dendritic metal alloy structures. These Sn-based electrodes have been evaluated for use as anodes in lithium-ion batteries. Dendritic Ni50Sn50 alloy foam exhibits high electrochemical capacity and excellent cycle stability during charge -discharge processes. The nickel in a Ni-Sn alloy does not break off during the volume expansion/contraction sequence in battery operation cycles and supports the Sn remaining on the anodes. The voids in the tube-like porous Ni-Sn morphology enhance the mass transfer of Li+ ions and act as mechanical bumpers during the charge discharge processes. (C) 2013 Elsevier B.V. All rights reserved.
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