期刊
JOURNAL OF POWER SOURCES
卷 238, 期 -, 页码 157-164出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2013.03.051
关键词
Platinum; Manganese oxide; Poly(3,4-ethylenedioxythiophene); Carbon nanotubes; Methanol electrooxidation
资金
- National Natural Science Foundation of China [21263002]
- Guangxi Natural Science Foundation of China [0991093, 2010GXNSFF013001]
- Foundation Project of Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Guangxi Normal University), Ministry of Education of China [CMEMR2012-A3]
We herein report a novel Pt-based electrocatalyst for direct methanol fuel cells (DMFCs) using multi-walled carbon nanotubes (MWCNTs) supported manganese oxide and poly(3,4-ethylenedioxythiophene) (PEDOT) nanocomposite (MnOx-PEDOT-MWCNTs) as catalyst support for Pt nanoparticles. The prepared nanocomposites are characterized by Fourier transform infrared (FIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and electrochemical tests. The results demonstrate that Pt nanoparticles are uniformly deposited on the surface of MnOx-PEDOT-MWCNTs, and their dispersion and electrochemical active surface area (ECSA) are obviously improved. The methanol electrooxidation activity and stability of the Pt/MnOx-PEDOT-MWCNTs are significantly enhanced as compared with the Pt/PEDOT-MWCNTs and Pt/MWCNTs catalysts. This study implies that the as-prepared Pt/MnOx-PEDOT-MWCNTs will be a promising candidate as an anode electrocatalyst in DMFCs. (c) 2013 Elsevier B.V. All rights reserved.
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