期刊
JOURNAL OF POWER SOURCES
卷 198, 期 -, 页码 423-427出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2011.09.074
关键词
Pyrolysis graphene; Graphite oxide; Oxygen-containing groups; Electrical conductivity; Specific capacitance
资金
- Shanghai Municipal Education Commission [10YZ03, 10YZ05]
- Natural Science Foundation of Shanghai [09ZR1411800, 10ZR1411300]
- Shanghai Key Laboratory of Green Chemistry and Chemical Processes (ECNU)
- Laboratory of Chemical Engineering (ECUST)
- Shanghai Leading Academic Discipline Project [S30109]
In this paper, graphene sheets with different reduction levels have been produced through thermal reduction of graphene oxide in the temperature range of 200-900 degrees C. The effects of interlayer spacing, oxygen content, BET specific surface area and disorder degree on their specific capacitance were explored systematically. The variation of oxygen-containing groups was shown to be a main factor influencing the EDL capacitor performances of the pyrolytic graphene. The highest capacitance of 260.5 F g(-1) at a charge/discharge current density of 0.4 A g(-1) was obtained for the sample thermally reduced at about 200 degrees C. (C) 2011 Elsevier By. All rights reserved.
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