期刊
JOURNAL OF POWER SOURCES
卷 217, 期 -, 页码 77-84出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2012.05.117
关键词
Tin-based anode; Lithium phosphate; Lithium-ion battery; Solid-state reaction; Thermal stability
资金
- National Natural 374 Science Foundation of China [20925312]
- State Key Basic 375 Research Program of PRC [2011CB935903]
- Shanghai Science & 376 Technology Committee [10JC1401500, 377 08DZ2270500]
Li3PO4, with a Li ion conductivity of 8.62 x 10-(8) S cm(-2), is considered as a matrix material in this study to improve the cyclability of tin anodes. Toward this goal, a well-crystallized NASICON-structured LiSn2(PO4)(3) using nano-SnO2 as a precursor has been prepared at 900 degrees C using a solid-state reaction. Compared to SnO2, this material exhibits better cycling performance, with a capacity of 320 mAh g(-1) after 50 cycles. Additionally, the insertion/extraction mechanism of LiSn2(PO4)(3) is investigated through ex-situ X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS) measurements. The apparent diffusion coefficient (D-Li) is studied using cyclic voltammetry (CV) experiments employing a powder microelectrode. In addition, differential scanning calorimetry (DSC) measurements are employed to investigate the thermal stability of LiSn2(PO4)(3). (C) 2012 Elsevier B.V. All rights reserved.
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