期刊
JOURNAL OF POWER SOURCES
卷 196, 期 19, 页码 8104-8109出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2011.05.038
关键词
Lithium ion battery; Lithium manganese phosphate; high-energy ball-milling; Electrochemical activity; Synchrotron radiation
Olivine lithium manganese phosphate (LiMnPO4) becomes research focus because of its high energy density and improved thermal stability. However, its application in lithium ion batteries suffers severely from poor electrochemical activity clue to low conductivity and structural instability upon the charge and discharge process. By applying a high-energy ball-milling method we succeed in improving the capacity delivery and rate capability. LiMnPO4 materials ball-milled without or with acetylene black are able to deliver a high capacity of 135 and 127 mAh g(-1), respectively, more than 50% greater than the pristine one. Particularly, the latter also shows an improved discharge plateau and stable cyclability. High-energy synchrotron radiation X-ray diffraction (XRD), scanning electron microscopy (SEM). Raman spectroscopy, laser particle analysis, and galvanostatic charge and discharge are employed to understand the effect of ball-milling on the LiMnPO4 material. (C) 2011 Elsevier B.V. All rights reserved.
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