期刊
JOURNAL OF POWER SOURCES
卷 196, 期 7, 页码 3548-3552出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2010.12.026
关键词
Highly ordered structure; Non-precious oxygen reduction catalyst; Performance
资金
- National Basic Research Program of China (973 Program) [2010CB933501]
- Innovative Youth Team of Natural Science Foundation of Zhejiang Province [R4090058]
- National Natural Science Foundation of China [51072182]
A highly ordered Pt-free Fe-N-C catalyst is synthesized through a hydrogen bonding-assisted self-assembly route. The catalyst has a porous structure with an average pore size of 5.5 nm and a large surface area of 416 m(2) g(-1), making it highly active in oxygen reduction. Cells assembled with the synthesized catalyst perform significantly better than those assembled with amorphous Fe-N-C cathode catalysts. The maximum powers of cells assembled from the highly ordered and amorphous catalysts are 252 and 60 mW cm(-2), respectively. (C) 2010 Elsevier B.V. All rights reserved.
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