期刊
JOURNAL OF POWER SOURCES
卷 196, 期 10, 页码 4609-4612出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2010.12.105
关键词
Palladium; Carbon nanofiber; Formic acid oxidation; Trisodium citrate
资金
- State Key Laboratory of Electroanalytical Chemistry
- Shanghai Key Laboratory of Green Chemistry and Chemical Process
- State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology (Zhejiang University of Technology)
Highly dispersed and active palladium/carbon nanofiber (Pd/CNF) catalyst is synthesized by NaBH4 reduction with trisodium citrate as the stabilizing agent. The obtained Pd/CNF catalyst is characterized by high resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). The results show that the Pd nanoparticles with an average particle size of ca. 3.8 nm are highly dispersed on the CNF support even with a small ratio of citrate to Pd precursor, which is believed to be due to the pH adjustment of citrate stabilized colloidal Pd nanoparticles. The cyclic voltammetry and chronoamperometry techniques show that the obtained Pd/CNF catalyst exhibits good catalytic activity and stability for the electrooxidation of formic acid. (C) 2011 Elsevier B.V. All rights reserved.
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