期刊
JOURNAL OF POWER SOURCES
卷 196, 期 8, 页码 4088-4094出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2010.12.059
关键词
Manganese oxide; Polythiophene; Mesoporous nanocomposite; Supercapacitor
资金
- National Basic Research Program of China (973 Program) [2009CB320301]
- National Natural Science Foundation of China [30901198]
Mesoporous nanocomposite of polythiophene and MnO2 has been synthesized by a modified interfacial method, aiming to develop electrode materials for supercapactitors with an enhanced cycle performance and high-rate capability. The N-2 adsorption/desorption isotherm test of the prepared hybrid indicates a high surface area and a typical mesoporous feature. A uniform hierarchical microstructure with submicron-spheres assembled from ultrathin nanosheet with diameters less than 10 nm has been confirmed by field-emission scanning electron microscopy and transmission electron microscopy. The employed interfacial synthesis is found to be advantageous to retard the overgrowth of nuclei. The retention of 97.3% of its initial capacitance after 1000 cycles at a charge/discharge rate of 2 A g(-1) indicates excellent cycle performance of the nanocomposite electrode. At a high-rate charge/discharge process of 10 A g(-1), the nanocomposite electrode retained 76.6% of its capacitance at 1 A g(-1), suggesting good high-power capability. The important roles of polythiophene in the as-prepared nanocomposite are highlighted in terms of their functions on enhancing the electrical conductivity and constraining the dissolution of manganese oxides during charge-discharge cycles. (C) 2010 Elsevier B.V. All rights reserved.
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