Pseudo-capacitance of composite electrode of ruthenium oxide with porous carbon in non-aqueous electrolyte containing imidazolium salt

Pseudo-capacitance of composite materials where ruthenium oxide particles are loaded on activated carbon has been evaluated in the electrolyte of 1-ethyl-3-methyl imidazolium tetrafluoroborate dissolved in acetonitrile. The composite materials prepared by conventional a sol-gel method have dispersed structure of ruthenium oxide particle of tens nanometer diameter on the surface of activated carbon. The extent of the pseudo-capacitance of the composite electrodes in the imidazolium salt electrolyte, estimated by the comparison of the capacitance per surface area of electrode in different non-aqueous electrolyte, is ca. 3-5 mu F cm(-2) in addition to the double-layer capacitance of ca. 6 mu F cm(-2), depending on the loading status of ruthenium oxide. The symmetric cell consisting of the composite electrode containing 18 wt% of ruthenium oxide and the imidazolium salt electrolyte provides cell capacitance based on the pseudo-capacitance by a constant-current test. (c) 2009 Elsevier B.V. All rights reserved.