期刊
JOURNAL OF POWER SOURCES
卷 195, 期 7, 页码 2074-2076出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2009.10.029
关键词
Ionic liquid; Lithium battery; C3mpyr; C4mpyr; Conductivity; Ab initio
资金
- Swedish Energy Agency
- Swedish Research Council
- Stiftelsen Futura
- European Commission [TST4-CT-2005-518307]
- ILLIBATT [NMP3-CT-2006-033181]
Ionic conductivity is a fundamental property of ionic liquids with its origin and exact nature under debate. Using a specially selected system of pyrrolidinium cations (PYR1x, x = 3,4) and sulfonylimide anions (FSI, TFSI, BETI, and IM14)-based ionic liquids we observe a simple and accurate connection between ab initio computed cation and anion volumes and measured molar ionic conductivities. (C) 2009 Elsevier B.V. All rights reserved.
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