期刊
JOURNAL OF POWER SOURCES
卷 195, 期 21, 页码 7484-7488出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2010.05.043
关键词
Electrochemical double layer capacitor; Ionic liquid; Temperature effects
资金
- EPSRC [EP/D031672/1]
- Engineering and Physical Sciences Research Council [EP/H019596/1, EP/D031672/1] Funding Source: researchfish
- EPSRC [EP/D031672/1, EP/H019596/1] Funding Source: UKRI
An electrochemical double layer capacitor test cell containing activated carbon xerogel electrodes and ionic liquid electrolyte was tested at 15, 25 and 40 degrees C to examine the effect of temperature on electrolyte resistance (R(S)) and equivalent series resistance (ESR) measured using impedance spectroscopy and capacitance using charge/discharge cycling. A commercial 10 F capacitor was used as a comparison. Viscosity, ionic self-diffusion coefficients and differential scanning calorimetry measurements were used to provide an insight into the behaviour of the 1,2-dimethy1-3-propylimdazolium electrolyte. Both R(S) and ESR decreased with increasing temperature for both capacitors. Increasing the temperature also increased the capacitance for both the test cell and the commercial capacitor but proportionally more for the test cell. An increase in temperature decreased the ionic liquid electrolyte viscosity and increased the self-diffusion coefficients of both the anion and the cation indicating an increase in dissociation and increase in ionic mobility. (C) 2010 Elsevier B.V. All rights reserved.
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