期刊
JOURNAL OF POWER SOURCES
卷 189, 期 1, 页码 585-589出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2008.10.050
关键词
Mesoporous materials; Anatase TiO2; Electrochemical lithium insertion
A metal film of Cu or Sn was vacuum-deposited on the surface of mesoporous anatase TiO2 electrodes, and the Li insertion/extraction behaviour was investigated by cyclic voltammetry and galvanostatic cycling. The morphological and structural characterization of metal-coated electrodes showed that the metallic layers do not alter the structure of anatase. The electrode surface modification made by thin-film deposition improves the kinetics of Li insertion/extraction and remarkably enhances the electrochemical performances in terms of capacity and stability, especially at high charge/discharge rates. (c) 2008 Elsevier B.V. All rights reserved.
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