期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 15, 期 5-6, 页码 421-432出版社
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424611003379
关键词
dodecaphenylporphyrin; hydrogen bonding; supramolecules; photovoltaics
资金
- JSPS [21350035, 20108010, P09049]
- MEXT
- National High Technology Research and Development Program for Advanced Materials of China [2009AA03Z220]
- Grants-in-Aid for Scientific Research [22750118, 21350035] Funding Source: KAKEN
A saddle-distorted porphyrin bearing a carboxyl group as a hydrogen-bonding site on a meso-phenyl group was synthesized and characterized. A supramolecular structure with intermolecular hydrogen bonding was revealed by X-ray diffraction analysis. The effects of the peripheral carboxyl group on the physicochemical properties of the porphyrin as well as on self-assembly were investigated by spectroscopic measurements in solutions. The redox properties of the porphyrin and its Zn(II) complex were also studied by electrochemical measurements and their application to dye-sensitized solar cells was examined.
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