期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 12, 期 9, 页码 1005-1021出版社
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1088424608000388
关键词
photosensitizer; electrocatalysis; phthalocyanine; quantum dots; carbon nanotubes
资金
- Department of Science and Technology (DST)
- National Research Foundation (NRF), South Africa through DST/NRF South African Research Chairs Initiative for Professor of Medicinal Chemistry and Nanotechnology
- Rhodes University
- Medical Research Council of South Africa
Electrocatalytic or photosensitizing (photocatalytic) properties of metallophthalocyanine (MPc) complexes are dependent on the central metal. Electrocatalytic behavior is observed for electroactive central metals such as Co, Mn and Fe, whereas photosensitizing behavior is observed for diamagnetic metals such as Al, Zn and Si. In the presence of nanoparticles such as quantum dots, the photosensitizing behavior of MPc complexes is improved. Carbon nanotubes enhance the electrocatalytic behavior of MPc complexes. Copyright (C) 2008 Society of Porphyrins & Phthalocyanines.
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