期刊
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
卷 51, 期 24, 页码 1736-1742出版社
WILEY
DOI: 10.1002/polb.23149
关键词
alkaline fuel cell; anion exchange membrane; guanidinium; imidazolium; ionomers; membrane; sidechain; stability; stabilization
资金
- Laboratory Directed Research and Development (LDRD) program at Sandia National Laboratories
- US Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000]
Anion exchange membranes comprised of a poly(phenylene) backbone and one of five different cationic head-groups are prepared, briefly characterized, and tested for stability in 4 M KOH at 90 degrees C. The two membranes with resonance-stabilized cations (benzyl pentamethylguanidinium and benzyl N-methylimidazolium) show large (>25%) decreases in both conductivity and ion exchange capacity (IEC) after just one day of testing. The membrane with benzyl trimethylammonium cations shows a 33% loss of conductivity (14% decrease in IEC) after 14 days while the membrane with trimethylammonium cations attached by a hexamethylene spacer shows the least degradation: a 5% loss of conductivity over 14 days with no accompanying loss in IEC. A similar membrane which has a six-carbon spacer and a ketone adjacent to the phenyl ring shows much lower stability, suggesting that the ketone takes part in degradation reactions. (c) 2012 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013, 51, 1736-1742, 2013
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