期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 52, 期 1, 页码 7-11出版社
WILEY-BLACKWELL
DOI: 10.1002/pola.26981
关键词
adhesives; polybenzoxazines; renewable resources; thermal properties
A novel renewable based benzoxazine, 3-(furan-2-ylmethyl)-8-methoxy-3,4-dihydro-2H-1,3-benzoxazine-6-formyl (Va-Bz), has been synthesized from a lignin derived chemical vanillin without solvents. Poly (Va-Bz) has high Tg and excellent thermal and adhesive properties. A mechanism of cross-linking, due to electrophilic substitution at furan and decarboxylation of carboxylic group of benzene ring, is suggested. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 7-11
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