期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 51, 期 9, 页码 1999-2005出版社
WILEY
DOI: 10.1002/pola.26580
关键词
all-polymer solar cells; conjugated polymers; copolymerization; high performance polymers; monomers; naphthalene diimides; open circuit voltages; organic photovoltaics; renewable resources; thin films
资金
- National Science Foundation of China [51173186]
- Chinese Academy of Sciences
- Natural Science Foundation of Fujian Province [2011J05040]
An angular-shaped naphthalene tetracarboxylic diimide (NDI) was designed and synthesized as a new building block for n-type conjugated polymers to tune their energy levels. Three n-type copolymers incorporating this angular-shaped NDI as the acceptor moiety were obtained by Stille coupling reactions and had number average molecular weights of 18.773.0 kDa. All-polymer bulk-heterojunction solar cells made from blends of these polymers with poly(3-hexylthiophene) gave a power conversion efficiency up to 0.32% and exhibited an open-circuit voltage (Voc) up to 0.94 V due to their relative high-lying lowest unoccupied molecular orbital energy levels. The high Voc of 0.94 V is higher than that of solar cells based on linear-shaped NDI-containing polymers (<0.6 V). The results indicate that the angular-shaped NDI is a promising building block for constructing nonfullerene polymer acceptors for solar cells with high open-circuit voltages. (c) 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013, 51, 1999-2005
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