期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 50, 期 7, 页码 1394-1407出版社
WILEY
DOI: 10.1002/pola.25907
关键词
atom transfer radical polymerization (ATRP); battery material; nitroxide mediated polymerization (NMP); organic radical battery; radical polymerization; reversible addition fragmentation chain transfer polymerization (RAFT); secondary amine; TEMPO polymer
资金
- Bundesministerium fur Bildung und Forschung [13N11393]
- TAB Thueringa
- TMWAT
- Dutch Polymer Institute (DPI, technology area HTE)
This work describes the polymerization of the free secondary amine bearing monomer 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPMA) by means of different controlled radical polymerization techniques (ATRP, RAFT, NMP). In particular, reversible addition-fragmentation chain transfer (RAFT) polymerization enabled a good control at high conversions and a polydispersity index below 1.3, thereby enabling the preparation of well-defined polymers. Remarkably, the polymerization of the secondary amine bearing methacrylate monomer was not hindered by the presence of the free amine that commonly induces degradation of the RAFT reagent. Subsequent oxidation of the polymer yielded the polyradical poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate), which represents a valuable material used in catalysis as well as for modern batteries. The obtained polymers having a molar mass (Mn) of 10,00020,000 g/mol were used to fabricate well-defined, radical-bearing polymer films by inkjet- printing. (c) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
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