期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 50, 期 24, 页码 5170-5176出版社
WILEY
DOI: 10.1002/pola.26361
关键词
functionalization of polymer; polyphosphazene; steric effect; thiol-ene
资金
- National Natural Science Foundation of China [21274126]
- Zhejiang Provincial Natural Science Foundation of China [Y4100146]
- Opening Foundation of Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), Ministry of Education [2012001]
- Zhejiang Provincial Top Key Discipline of New Materials and Process Engineering [20110915]
The thiolene radical addition reaction has been successfully used to synthesize polyphosphazene derivatives. Poly[bis(allylamino)phosphazene] with pendant allyl groups was reacted with different thiol reagents under UV irradiation. These thiol reagents include 1-pentanethiol, 3-mercaptopropionic acid, 3-mercapto-1,2-propane-diol, and 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranose. 1H NMR analyses confirm that the allyl polyphosphazene can be quantitatively modified by the mercaptans. In total, 100% conversion of the allyl groups was reached in <60 min toward the first three mercaptans, whereas about 80% conversion of the allyl groups was reached after 120-min reaction toward the thioglucose. This method is a facile route for the synthesis of functional polyphosphazenes without the needs for protection/deprotection procedures. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据