期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 50, 期 6, 页码 1127-1132出版社
WILEY
DOI: 10.1002/pola.25870
关键词
acid catalysis; conducting polymers; catalysis; decarboxylation; ester cleavage; low temperature; polythiophene ester; primary ester; secondary ester; solubility switching; tertiary ester; thermocleavage; thermogravimetric analysis (TGA)
资金
- Danish Strategic Research Council [DSF 2104-07-0022]
Solubility switching of polymers is very useful in thin layer processing of conjugated polymers, as it allows for multilayer processing and increases the stability of the polymer. Acid catalyzed thermocleavage of ester groups from thiophene polymers carrying primary, secondary, and tertiary substituents have been examined by TGA-MS using different sulphonic acids. A substantial lowering of the cleavage temperature is observed, and the ester cleavage can even be performed in situ on roll-to-roll-coated films on polyethylene terephthalate (PET). (c) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
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