期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 49, 期 7, 页码 1597-1604出版社
WILEY
DOI: 10.1002/pola.24583
关键词
cationic ring-opening (co) polymerization; click chemistry; polyurethanes
资金
- FWO (Fund for Scientific Research Flanders, Belgium)
- IWT (The Institute for the Promotion of Innovation through Science and technology in Flanders, Belgium)
A straightforward strategy for the synthesis and functionalization of polyurethanes (PUs) via the use of alkyne-functionalized polytetrahydrofuran (PTHF) diols is described. The alkyne groups have been introduced into the PTHF chains by the cationic ring-opening copolymerization of tetrahydrofuran and glycidyl propargyl ether. These PTHF prepolymers were combined with 1,4-butanediol and hexamethylene diisocyanate for the synthesis of linear PUs with latent functionalization sites. The polyether segments of the PUs have then been coupled with several types of functionalized azides by the copper-catalyzed azide-alkyne click'' chemistry, for example with phosphonium containing azides for their antibacterial properties. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 1597-1604, 2011
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