期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 48, 期 7, 页码 1669-1675出版社
WILEY
DOI: 10.1002/pola.23931
关键词
conjugated polymers; copolymerization; diketo-pyrrolo-pyrrole; heteroatom-containing polymers; solar cell
资金
- National Science Council [NSC 98-2120M-009-006]
We have synthesized a narrow-bandgap conjugated polymer (PCTDPP) containing alternating cyclopentadithiophene (CT) and diketo-pyrrolo-pyrrole (DPP) units by Suzuki coupling. This PCTDPP exhibits a low band gap of 1.31 eV and a broad absorption band from 350 to 1000 nm, which allows it to absorb more available photons from sunlight. A bulk hetero-junction polymer solar cell incorporating PCTDPP and C-70 at a blend ratio of 1:3 exhibited a high short-circuit current of 10.87 mA/cm(2) and a power conversion efficiency of 2.27%. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1669-1675,2010
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