期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 47, 期 12, 页码 2959-2976出版社
WILEY
DOI: 10.1002/pola.23351
关键词
enzymes; esterification; functionalization of polymers; green polymer chemistry; Michael addition
资金
- National Science Foundation [DMR-0509687, 0804878, CHE-0341701, DMR-0414599]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0804878] Funding Source: National Science Foundation
The use of enzymes as catalysts for organic synthesis has become an increasingly attractive alternative to conventional chemical catalysis. Enzymes offer several advantages including high selectivity, to operate under mild ability conditions, catalyst recyclability, and biocompatibility. Although there are many examples in the literature involving enzymes for the synthesis of polymers, our search showed that very little had been done in the area of polymer modification. In this article, we will discuss enzyme catalysis in general and highlight our recent results concerning precision polymer function-alization using enzymatic catalysis -green polymer chemistry. (C) 2009 Wiley Periodicals. Inc. J Polym Sci Part A: Polym Chem 47: 2959-2976, 2009
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