期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 46, 期 9, 页码 2897-2912出版社
WILEY
DOI: 10.1002/pola.22627
关键词
catalysis; monomers; radical polymerization; structure-property relations
Synthetic strategies for the preparation of a new family of vinyl monomers, 4-vinyl-1,2,3-triazoles, have been developed. These monomers are noteworthy as they combine the stability and aromaticity of styrenics with the polarity of vinyl-pyridines and the structural versatility of acrylate/methacrylate derivatives. To enable the wide adoption of these unique monomers, new methodologies for their synthesis have been elaborated which rely on Cu-catalyzed azide/acetylene cycloaddition reactions-click chemistry-as the key step, with the vinyl substituent being formed by either elimination or Wittig-type reactions. In addition, one-pot click reactions have been developed from alkyl halides, which allow for monomer synthesis without isolation of the intermediate organic azides. The high yield and facile nature of these procedures has allowed a library of new monomers including the parent compound, 1-H-4-vinyl-1,2,3-triazole, to be prepared on large scales. (C) 2008 Wiley Periodicals, Inc.
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