期刊
JOURNAL OF POLYMER RESEARCH
卷 20, 期 7, 页码 -出版社
SPRINGER
DOI: 10.1007/s10965-013-0182-9
关键词
Sulfonated poly (aryl ether sulfone); PEMFC; 2,5-bis(4-fluorophenyl)-1,3,4-oxadiazole; Proton conductivity
资金
- Natural Science Foundation of China [51273024]
- Department of Education of Jilin Province [2012103]
Double fluoride 2,5-bis(4-fluorophenyl)-1,3,4-oxadiazole (BFO) monomer was synthesized. Copolymerization of BFO, 2,2-bis(4-hydroxypheny) propane (bisphenol A) and 3'3-disulfonate-4'4-dichloro dipheny sulfone (SDCDPS) at different molar ratio resulted in a new poly (aryl ether sulfone) containing 1, 3, 4-oxadiazole polymers (SPAESO). The structures of monomer BFO and copolymer were confirmed by FT-IR and H-1 NMR. The TEM pictures showed that the ion clusters were formed and distributed evenly in SPAESO copolymer matrix. The sulfonated polyoxadiazole membranes exhibited excellent thermal, dimensional and oxidative stability and lower methanol diffusion coefficient. The proton conductivity of SPAESO-3 was 7.5x10(-2) Scm(-1) at 120 degrees C while the methanol permeability coefficient of SPAESO-3 was only 2.23x10(-7) cm(2)S(-1) at 25 degrees C. According to the comprehensive performance, the sulfonated polyoxadiazole membranes may be the alternative materials as proton exchange membrane for PEMFC at medium-high temperature operation.
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