期刊
JOURNAL OF POLYMER RESEARCH
卷 18, 期 6, 页码 2017-2021出版社
SPRINGER
DOI: 10.1007/s10965-011-9610-x
关键词
Barium ferrite fibers; Poly(vinylidene fluoride) (PVDF); Composite films; Magnetic property; Dielectric property
资金
- National Natural Science Foundation of China [50674048]
- China Postdoctoral Science Foundation [20090451169]
- Research Fund for the Doctoral Program of Higher Education of China [20103227110006]
- Jiangsu Province's Postgraduate Cultivation and Innovation Project [CX10B-257Z]
Barium ferrite fibers/poly(vinylidene fluoride) (BaFe12O19/PVDF) composite films were prepared from poly(vinylidene fluoride) (PVDF) resin with different weight percentages (1, 5, 10, 20, 30 wt%) of M-type barium ferrite fibers using N,N-dimethylformamide as a solvent. The structure and morphology of the BaFe12O19/PVDF composite films were characterized by scanning electron microscopy and X-ray diffraction. These results show that BaFe12O19 fibers with diameters around 1 mu m and an aspect ratio (length/diameter) of about 50 are well dispersed in the PVDF resin and the dispersed fibers result in a structural change of the PVDF from alpha to beta phase. Measurements of the magnetization of the composite films by using a vibrating sample magnetometer show that these BaFe12O19/PVDF composite films possess a hard magnetic characteristic. The specific saturation magnetization and dielectric loss increase with BaFe12O19 content, whereas the coercivity and dielectric constant of the composite films are less affected. These BaFe12O19/PVDF composite films can combine magnetic, dielectric, and mechanical properties of the BaFe12O19 and PVDF phases.
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