期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 29, 期 4, 页码 209-215出版社
WILEY
DOI: 10.1002/aoc.3270
关键词
metal-organic framework; tin(IV) porphyrin; MIL-101(Cr); trimethylsilylation; tetrahydropyranylation
资金
- Research Council of the University of Isfahan
The catalytic activity of 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [Sn-IV(TNH2PP)(OTf)(2)], supported on chloromethylated MIL-101, was investigated in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) and also their tetrahydropyranylation with 3,4-dihydro-2H-pyran. Excellent yields, mild reaction conditions, short reaction times and reusability of the catalyst without significant decrease in its initial activity are noteworthy advantages of this supported catalyst. Copyright (c) 2015 John Wiley & Sons, Ltd.
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