4.2 Article

Tensorial form and matrix elements of the relativistic nuclear recoil operator

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IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/44/17/175003

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  1. 'Fonds pour la formation a la Recherche dans l'Industrie et dans l'Agriculture' of Belgium
  2. Communaute francaise of Belgium (Action de Recherche Concertee)
  3. Belgian National Fund for Scientific Research (FRFC/IISN Convention)

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Within the lowest-order relativistic approximation (similar to v(2)/c(2)) and to first order in m(e)/M, the tensorial form of the relativistic corrections of the nuclear recoil Hamiltonian is derived, opening interesting perspectives for calculating isotope shifts in the multiconfiguration Dirac-Hartree-Fock framework. Their calculation is illustrated for selected Li-, B- and C-like ions. This work underlines the fact that the relativistic corrections to the nuclear recoil are definitively necessary for obtaining reliable isotope shift values.

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