期刊
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
卷 72, 期 4, 页码 263-268出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2011.01.004
关键词
Glasses; Crystal growth; Raman spectroscopy; Phase transitions
资金
- Ministry of Education, Science, Sports, Culture and Technology, Japan
- Nagaoka University of Technology
- Ministry of Education and Science of Bulgaria, The National Science Fund of Bulgaria [TK-X-1718/07]
- Grants-in-Aid for Scientific Research [23246114] Funding Source: KAKEN
The ternary MoO3-La2O3-B2O3 glasses containing a large amount of MoO3 (10-50 mol%) are prepared, and their structure and crystallization behavior are examined from the Raman scattering spectrum measurements and X-ray diffraction analyses. It is found that the glass transition and crystallization temperatures and the thermal stability against crystallization decrease with increasing MoO3 content. It is suggested that the main coordination state of Mo6+ ions in the glasses is isolated (MoO4)(2-) tetrahedral units giving strong Raman bands at 830-860 and 930 cm(-1). It is found that the crystalline phases in the crystallized glasses are mainly LaMoBO6 and LaB3O6, and the main crystallization mechanism in MoO3-La2O3-B2O3 glasses is surface crystallization. LaMoBO6 crystals are found to give strong Raman bands at 810-830 and 910 cm(-1). (C) 2011 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据