期刊
PHYSICAL REVIEW LETTERS
卷 115, 期 2, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.115.023201
关键词
-
资金
- NSERC of Canada
We develop a theoretical method for solving the quantum mechanical reactive scattering problem in the presence of external fields based on a hyperspherical coordinate description of the reaction complex combined with the total angular momentum representation for collisions in external fields. The method allows us to obtain converged results for the chemical reaction LiF + H -> Li + HF in an electric field. Our calculations demonstrate that, by inducing couplings between states of different total angular momenta, electric fields with magnitudes < 150 kV/cm give rise to resonant scattering and a significant modification of the total reaction probabilities, product state distributions, and the branching ratios for reactive versus inelastic scattering.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据