期刊
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
卷 26, 期 3, 页码 274-279出版社
WILEY
DOI: 10.1002/poc.3081
关键词
Ar-BIAN ligands; cyclic voltammetry; UVVis spectroscopy
资金
- Canadian Foundation for Innovation
- National Sciences and Engineering Research Council of Canada
- Le Fonds quebecois de la recherche sur la nature et les technologies
- Universite de Sherbrooke
Herein, we report the synthesis and electrochemical and spectroscopic characterization for a series of six bis(arylimino)acenaphthene, compounds commonly used as ligands in catalysis, polymerization and materials. Low energy absorption bands are the result of an intraligand charge transfer between the aryl groups and the acenaphthene core, and their energies obey a Hammett relationship with respect to substitution on the aryl. Copyright (c) 2013 John Wiley & Sons, Ltd.
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