期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 5, 期 2, 页码 363-369出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz402510a
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资金
- National Basic Research Program of China [2013CB934800]
- National Natural Science Foundation of China (NSFC) [21073083, 21373086, 21103050, 21222302]
- NSFC-Royal Society Joint Program [21111130201]
- Program for New Century Excellent Talents in University [NCET-10-0483]
- Fundamental Research Funds for the Central Universities [1124020512]
- National Science Fund for Talent Training in Basic Science [J1103310]
- Scientific Research Foundation of the Graduate School of Nanjing University [2012CL05]
By using a simple and efficient deuteration process, H-2 has been successfully introduced into layered double hydroxides (LDHs). Due to significantly less H-1-H-1 homonuclear dipolar coupling, high-resolution H-1 solid-state NMR spectra can now be obtained conveniently at medium to low spinning speed to extract the information of cation ordering in LDHs. Furthermore, we show that double-resonance experiments can be applied easily to investigate internuclear proximities and test possible cation-ordered superstructure models. This approach can be readily extended to LDHs with different compositions to explore the local structure and the key interactions between the cations in the layer and interlayer anions.
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