期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 4, 期 23, 页码 4160-4165出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz402090d
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资金
- National Science Foundation [OCI-1053575]
First-principles investigations of the electrocatalytic activity toward the four-electron oxygen reduction-reaction in N-doped graphene quantum dots reveal that pyridinic and graphitic nitrogen are the most active sites with overpotentials of 0.55 and 0.79-0.90 V, respectively. This agrees with experimental findings. Our calculations account for van der Waals interactions, solvent effects, and describe the electrochemistry using standard hydrogen electrode model. The results show correlations between OH*, OOH*, and O* binding energies that impose a lower limit on the oxygen reduction overpotential.
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