期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 4, 期 11, 页码 1834-1837出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz400715r
关键词
-
类别
资金
- Australian Research Council (ARC) through the ARC Centre of Excellence for Electromaterials Science (ACES)
- Australian Research Council under the Australian Laureate and Federation
Stable electrogenerated superoxide ion has been observed for the first time in a phosphonium-based ionic liquid in the presence of water, leading to a chemically reversible O-2/O-2(center dot-) redox couple instead of the disproportionation reaction that is usually observed. It appears that the cation solvates the superoxide anion, stabilizing it against the disproportionation reaction. The electrogeneration is studied at various levels of water or other diluents including toluene to explore the limits of stability of the superoxide ion under these conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据