期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 4, 期 23, 页码 4074-4079出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz4021537
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资金
- NSF [CHE-1058063]
- Deutsche Forschungsgemeinschaft (DFG) [GA 370/5-1, TH 1301/3-1, TH 1301/3-2]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1058063] Funding Source: National Science Foundation
The rotational spectrum of hydroxidooxidosulfur, HOSO, an intermediate of particular interest in the combustion of sulfur-rich fuels, has been determined to high accuracy from gas-phase measurements. Detection of specific isotopic species using isotopically enriched gases suggests that HOSO is formed in our discharge nozzle via the reaction H + SO2 (+M) -> HOSO (+M). A precise experimental r(0) geometry has also been derived from the isotopic analysis; HOSO has a cis configuration, but the subtle structural question of its planarity remains unresolved. From the derived spectroscopic constants, in situ and remote sensing for this fundamental radical can now be undertaken in a variety of environments, including in combustion reactors, the troposphere of Earth, and Io, the innermost Galilean moon of Jupiter.
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