期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 4, 期 14, 页码 2279-2283出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz400978g
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资金
- Ministry of Education, Culture and Sports
- Grants-in-Aid for Scientific Research [25513012] Funding Source: KAKEN
Solid-state dipolar dephasing filtered (DDF)-INADEQUATE experiments were used to detect the hemicellulosic signals of lignocellulosic mixtures; here dipolar dephasing was used as a signal filter to remove signals derived from cellulose. The maximum filtering efficiency was obtained when the dephasing time was adjusted to half the rotor period at a magic-angle spinning (MAS) frequency of 12 kHz, which indicated that the molecular motions in hemicelluloses are faster than those in cellulose. In a DDF-INADEQUATE spectrum of uniformly C-13-labeled lignocellulose from corn (Zea mays) collected with a dephasing time of 1/2v(MAS), the chemical shifts of beta-D-xylopyranose (Xylp) and alpha-L-arabinofuranose (Araf) in glucuronoarabinoxylan, the major hemicellulose in the secondary cell walls of the gramineous plant, were assigned.
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