期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 4, 期 4, 页码 583-588出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz4001642
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资金
- JNCASR, the Department of Biotechnology (DBT)-Innovative Young Biotechnologist Award (IYBA), India
Serendipitously, we found that isoleucine methylester functionalized perylenediimide 1 undergoes an extremely slow supramolecular helical assembly over a day's time. Surprisingly, heating led to irreversible chiral denaturation. However, reversible helical assembly could be achieved only in the presence of nondenatured aggregates of 1, which act as seeds. The intriguing functional relevance deduced from 1 was employed to draw parallels with the secondary structure of proteins, envisaging its plausible implications.
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