期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 3, 期 2, 页码 209-213出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz201504k
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- Alexander von Humboldt Foundation
Nanoporous functionalized graphene membranes containing nitrogen atoms in a nanosized ring pore have the capability to separate He-3 from He-4 efficiently by quantum tunneling through the pore. Calculations on size-reduced model systems of single-graphene pores reveal that a balanced choice of tunneling barrier height and low gas temperature boosts the selectivity and keeps the helium gas flux at an industrially exploitable level.
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