期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 3, 期 7, 页码 834-838出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz3000933
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资金
- EPSRC [EP/D073472/1]
- Durham University
- Leverhulme Trust
- Engineering and Physical Sciences Research Council [EP/D073472/1] Funding Source: researchfish
- EPSRC [EP/D073472/1] Funding Source: UKRI
The first time-resolved photoelectron imaging study of a polyanion is presented. Using the alignment induced through resonance excitation, the photoelectron angular distributions can be qualitatively understood in terms of the position of localized excess charges on the molecular skeleton, which influence the photoemission dynamics. Pump-probe experiments are used to demonstrate that the photoelectron angular distribution is also sensitive to molecular dynamics. This is shown here for the rotational dynamics of a polyanion, in which the photoelectron anisotropy tracks the rotational coherence as it dephases. The methodology can in principle be applied to general molecular dynamics in large polyanions, providing a new route to studying ultrafast structural dynamics in complex gas-phase systems.
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