期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 2, 期 8, 页码 926-931出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz200272r
关键词
-
类别
资金
- Ministere de la Defense, Direction Generale de l'Armement DGA [DGA-REI 07 34024]
The grafting of stimuli-responsive polymer brushes on plasmonic structures provides a perfectly controlled two-dimensional active device with optical properties that can be modified through external stimuli. Herein, we demonstrate thermally induced modifications of the plasmonic response of lithographic gold nanoparticles functionalized by thermosensitive polymer brushes of (poly(N-isopropylacrylamide), PNIPAM). Optical modifications result from refractive local index changes due to a phase transition from a hydrophilic state (swollen regime) to a hydrophobic state (collapsed regime) of the polymer chains occurring in a very small range of temperatures. The refract:ye index of the polymer in aqueous solution is estimated in both states, deduced from the discrete dipole approximation (DDA) method. The combination of lithographic gold NPs and thermoresponsive polymer chains leads to a new generation of perfectly calibrated and dynamically controlled hybrid gold/polymer system for real-time nanosensors.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据