期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 2, 期 24, 页码 3081-3084出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz201430h
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资金
- Swiss National Science Foundation [PP02_118930]
- BASF SE (Electronic Materials)
We present the first molecular model of the coordination complex formed by Cu(I) and imidazole-epichlorohydrin polymers. Our calculations show that the Cu(I) ion has linear coordination and the whole complex has neutral charge. Our model suggests salt couple pairing as the driving force for the formation of the surface-confined precipitation, which is crucial to obtain flat surfaces in industrial copper deposition processes, required for mass fabrication of state-of-the-art electronic and memory devices.
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