期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 2, 期 12, 页码 1359-1362出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz200524m
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资金
- Fondazione Cariplo [2009-2726]
- MIUR [2008J858Y7]
- European Union (EU)
Thermally annealed chiral polyfluorene films are studied by circular differential optical microscopy. We observe the presence of micrometer-sized domains displaying circular dichroism of opposite sign. Our findings suggest the spontaneous occurrence of left- and right-handed cholesterically ordered domains from an enantiopure precursor. The role of enantiopure stereo centers in the side chains of the polymer is to lower the energy of the left-handed cholesteric domains with respect to the right-handed ones.
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