4.8 Article

A New Solar Carbon Capture Process: Solar Thermal Electrochemical Photo (STEP) Carbon Capture

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JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 1, 期 15, 页码 2363-2368

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AMER CHEMICAL SOC
DOI: 10.1021/jz100829s

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  1. George Washington University

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The first experimental evidence of a new solar process, combining electronic and chemical pathways, to isolate CO2 (carbon capture) is presented. This solar thermal electrochemical photo (STEP) process is a synergy of solid-state and solar thermal processes, and is fundamentally capable of converting more solar energy than photovoltaic or solar thermal processes alone. Here, CO2 is captured using a 750-950 degrees C electrolysis cell powered by a full spectrum solar simulator in a single step. The process uses the full spectrum; solar thermal energy decreases the energy required for carbon capture, while visible sunlight generates electronic charge to drive the electrolysis. CO2 can be captured from 34% to over 50% solar energy efficiency (depending on the level of solar heat inclusion), as solid carbon and stored, or used as carbon monoxide to be available for a feedstock to synthesize (with STEP generated hydrogen) solar diesel fuel, synthetic jet fuel, or chemical production.

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