期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 1, 期 1, 页码 28-31出版社
AMER CHEMICAL SOC
DOI: 10.1021/jz9000449
关键词
Surfaces; Interfaces; Catalysis
类别
资金
- Airforce AFOSR - Ctr of Excellence on BIONIC [3306FF9]
Alumina and silica have been the most commonly, used solid supports in the recovery of colloidal nanocatalysts in solution. In order to avoid possible involvement of the support in the catalytic mechanism, polystyrene microspheres are here demonstrated to be effective and nonreactive supports on which the nanocatalyst can be easily attached by using the swelling and shrinking properties of the polystyrene microspheres. The activation energy of the reduction of 4-nitrophenol with sodium borohydride on platinum nanocubes free in solution is comparable to those on polystyrene microspheres.
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