期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 123, 期 13, 页码 7810-7817出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.8b06769
关键词
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资金
- Air Force Office of Scientific Research (AFOSR) [FA9550-15-1-0259]
- Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, U.S. Department of Energy
Results of photoelectron spectroscopy measurements and density functional theory complemented with correction scheme calculations on electron binding energy (EBE) spectra of anionic ALM, n = 3-5 and 7, clusters are presented and analyzed. The analysis points to the important role of dynamical fluxionality and multiplicity of structural forms as contributing factors in the measured spectra. Using the example of Al4Mo- as a paradigmatic case, the separate roles of size, structure/symmetry, and composition in evolving the EBE spectra of precursor pure clusters (in this case, Al-4(-) and Al-5(-)) into those of bimetallic clusters are demonstrated utilizing a new methodology we developed recently (J. Phys. Chem. C 2017, 121, 16665).
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