期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 118, 期 20, 页码 10998-11005出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp500556p
关键词
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资金
- National Science Foundation of China [21104044]
- National Basic Research Program of China (973 Program) [2013CB834704]
- Ph.D. Programs Foundation of Ministry of Education of China [20110073120040]
Multifunctional and mechanochromic optoelectronic materials are of significant importance in both academic and technical aspects. In this contribution, a novel D A conjugate (AN2TPAN), consisting of arylamine and two triphenylacrylonitrile (TPAN) units, with sterically crowded and remarkably twisted conformations, has been carefully designed and synthesized. It shows typical intramolecular charge transfer, aggregation-induced emission, and aggregation-enhanced two-photon absorption characteristics. Moreover, it exhibits more than three emission colors in the solid state upon mechanical grinding. Such multicolor mechanochromism for solid emitters under mild conditions is rarely reported. A multilayer nondoped OLED device of AN2TPAN is fabricated and performs excellently, whose maximal current and external quantum efficiencies are as high as 10.7 cd/A and 3.3%, respectively. The multifunctionality and multicolor mechanochromism of AN2TPAN make it promising in optoelectronic applications.
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