Inequivalence of Single-Particle and Population Lifetimes in a Cuprate Superconductor

We study optimally doped Bi-2212 (T-c = 96 K) using femtosecond time-and angle-resolved photoelectron spectroscopy. Energy-resolved population lifetimes are extracted and compared with singleparticle lifetimes measured by equilibrium photoemission. The population lifetimes deviate from the single-particle lifetimes in the low excitation limit by 1-2 orders of magnitude. Fundamental considerations of electron scattering unveil that these two lifetimes are in general distinct, yet for systems with only electron-phonon scattering they should converge in the low-temperature, low-fluence limit. The qualitative disparity in our data, even in this limit, suggests that scattering channels beyond electron-phonon interactions play a significant role in the electron dynamics of cuprate superconductors.