期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 118, 期 6, 页码 2970-2976出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp411382r
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资金
- Mitsubishi Motors Corporation
- Ministry of Education, Culture, Sports, Science and Technology, Japan
Na-ion batteries have been the subjects of intensive studies for grid-scale energy storage recently. O3-type NaFeO2 is a promising candidate for the Na-ion cathode materials, though the irreversibility during Na-ion extraction/insertion seriously hinders its practical application. The present work demonstrates that partial replacement of Fe in O-3-NaFeO2 with Ni leads to the significant improvement of the electrochemical properties. The Fe-57 Mossbauer and X-ray absorption spectra show that O3-type NaFeO2 NaNiO2 solid solution forms hybridized frontier orbital of a Fe-O-Ni bond via ligand-to-metal charge transfer, which plays a dominant role in the charge discharge process. The resulting O3-NaFe0.3Ni0.7O2 delivers an initial discharge capacity of 135 mA.h.g(-1), most of which is in a high-voltage region of 2.5-3.8 V, with a high initial Coulombic efficiency of 93%, and shows enhanced cycle stability.
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