期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 118, 期 17, 页码 9114-9118出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp412821w
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资金
- Center for Exploitation of Nanostructures in Sensor and Energy Systems (CENSES) under NSF [0833180]
- National Science Foundation [CHE-1041832]
- National Institute of Justice, Office of Justice Programs, U.S. Department of Justice [2009-DN-BX-K185]
- NSF PREM [DMR-0934206]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0934206] Funding Source: National Science Foundation
We present the observation of size-dependent surface-enhanced Raman spectra (SERS) for crystal violet (CV) adsorbed on a monolayer of hexagonally close-packed silica spheres. Enhancement factors on the order of 10(4) are estimated based on the ratio of the number of CV molecules excited in solution to those on the surface of the monolayer array. The proposed enhancement mechanism is that of delocalized surface plasmon resonance over the monolayer array. Plasmon resonances of silica spheres are calculated using Mie theory for light scattering and experimentally validated with UV-vis absorption spectra. There is an excellent agreement between the observed spectrum from the monolayer arrays and a single particle calculated spectrum. This work points the way to utilize silica particles as a viable alternative to current SERS substrates as well as illustrates the importance of surface plasmon resonances from photonic crystals in the SERS of semiconductors.
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